[27] Crystal Structure and Magnetic Characterization of Three-Coordinate [M{N(SiMe3)2}2(PCyp3)] Complexes with M = MnII, FeII, and CoII (Cyp = Cyclopentyl)

C. G. Werncke, L. Vendier, S. Sabo-Etienne, J.-P. Sutter, C. Pichon, S. Bontemps

Eur. J. Inorg. Chem. 2017, 2017, 1041-1406




[26] Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes,

C. Gunnar Werncke, Mohammed-Amine Bouammali, Julie Baumard, Nicolas Suaud, Cyril Martins,  Nathalie Guihéry,* Laure Vendier, Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel,  Sylviane Sabo-Etienne, Jean-Pascal Sutter, Sébastien Bontemps and Céline Pichon

Inorg. Chem. 2016, 55, 21, 10968-10977




[25] Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I)

C. Gunnar Werncke, Elizaveta Suturina, Philip C. Bunting, Laure Vendier, Jeffrey R. Long, Mihail Atanasov, Frank Neese,* Sylviane Sabo-Etienne and Sébastien Bontemps*

Chemistry, Eur. J. 2016, 22, 1668-1674. Abstract




[24] Boron-Mediated Activation of Carbon Dioxide

 S. Bontemps*

 Coord. Chem. Rev. 2016, 308, Part 2, 117-130. Abstract, Top 1% cited article November 2016 to June 2017




[23] Iron-Catalyzed C–H Borylation of Arenes

T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps, J.-B. Sortais, S. Sabo-Etienne, and C. Darcel

J. Am. Chem. Soc. 2015, 137, 4062–4065. Abstract, Top 1% cited article in Sept/Oct 2015.




[22] Two-Coordinate Iron(I) Complex [Fe{N(SiMe3)2}2]−: Synthesis, Properties, and Redox Activity

C. G. Werncke, P. C. Bunting, C. Duhayon, J. R. Long, S. Bontemps, S. Sabo-Etienne

Angew. Chem. Int. Ed. 2015, 54, 245-248. Abstract




[21] Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C Bonds

 G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne, S. Bontemps

 J. Am. Chem. Soc. 2015, 137, 9563–9566. Abstract




[20] Three bonding modes of bis(2-picolyl)phenylphosphine at iron: isolation of a dinuclear iron complex featuring dearomatized pyridine moieties

 G. Jin, L. Vendier, Y. Coppel, S Sabo-Etienne, S. Bontemps

 Dalton Trans. 2015, 44, 7500-7505. Abstract



[19] Ruthenium-Catalyzed Reduction of Carbon Dioxide to Formaldehyde

 S. Bontemps, L. Vendier, S. Sabo-Etienne,

 J. Am. Chem. Soc. 2014, 136, 4419–4425. Abstract, Top 1% cited article in May/June 2015.




[18] Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide

 S. Bontemps, S. Sabo-Etienne

 Angew. Chem. Int. Ed. 2013, 52, 10253-10255. Hot Paper. Abstract




[17] Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds

 S. Bontemps, L. Vendier and S. Sabo-Etienne

 Angew. Chem. Int. Ed. 2012, 51, 1671-1674.Abstract



[16] Comparative Reactivity of Zr– and Pd–Alkyl Complexes with Carbon Dioxide

K.-C. Lau, B. J. Petro, S. Bontemps, R. F. Jordan

Organometallics 2013, 32, 6895-6898. Abstract



[15] Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P→B Interactions

 S. Bontemps, M. Devillard, S. Mallet-Ladeira, G. Bouhadir, K. Miqueu, D. Bourissou

 Inorg. Chem. 2013, 52, 4714-4720. Abstract



[14] Palladium-Catalyzed Aryl Iodide Carbonylation as a Route to Imidazoline Synthesis: Design of a Five-Component Coupling Reaction

 S. Bontemps, J. S. Quesnel, K. Worrall, B. A. Arndtsen

 Angew. Chem. Int. Ed. 2011, 50, 8948-8951. Abstract



[13] A Palladium-Catalyzed Multicomponent Synthesis of Imidazolinium Salts and Imidazolines from Imines, Acid Chlorides and Carbon Monoxide

K.Worrall, B. Xu, S. Bontemps, B. A. Arndtsen

J. Org. Chem. 2011, 76, 170-180. Abstract



[12] A 1,1’-ferrocenyl phosphine-borane : synthesis, structure and evaluation in Rh-catalyzed hydroformylation

 M. W. P. Bebbington, S. Bontemps, G. Bouhadir, M. J. Hanton, R. P. Tooze, H. van Rensburg, D. Bourissou

 New J. Chem. 2010, 34, 1556-1559. Abstract



[11] Copper(I) Complexes derived from Mono- and Diphosphino-Boranes : Cu→B Interactions Supported by Arene Coordination

 M. Sircoglou, S. Bontemps, M. Mercy, K. Miqueu, S. Ladeira, N. Saffon, L. Maron, G. Bouhadir, D. Bourissou

 Inorg. Chem. 2009 ,49, 3983-3990. Abstract



[10] Bridging M-Cl Bonds with Ambiphilic Phosphine–Borane Ligands

 S. Bontemps, G. Bouhadir, D. Apperley, P. W. Dyer, K. Miqueu, D. Bourissou

 Chem. Asian J. 2009, 4, 428-435. Abstract



[9] Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane

 M. Sircoglou, S. Bontemps, G. Bouhadir, N. Saffon, K. Miqueu, W. Gu, M. Mercy, C-H. Chen, B. Foxman, L. Maron, O. Ozerov, D. Bourissou

 J. Am. Chem. Soc. 2008, 130, 16729-16738. Abstract



[8] Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes

 X. Zhou, S. Bontemps, R. F. Jordan

 Organometallics 2008, 27, 4821-4824. Abstract



[7] Metallaboratranes Derived from a Triphosphanyl-Borane : Intrinsic C3 Symmetry Supported by a Z-Type Ligand

 S. Bontemps, G. Bouhadir, W. Gu, M. Mercy, C-H. Chen, B. M. Foxman, L. Maron, O. Ozerov, D. Bourissou

 Angew. Chem. Int. Ed. 2008, 47, 1481-1484. Abstract



[6] Ambiphilic Diphosphine-Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium

 S. Bontemps, M. Sircoglou, G. Bouhadir, H. Puschmann, J. A. K. Howard, P. Dyer, K. Miqueu, D. Bourissou

 Chem. Eur. J. 2008, 14, 731-740. Abstract



[5] Transition-Metal Complexes Featuring Z-Type Ligands: Agreement or Discrepancy between Geometry and dn Configuration?

 M. Sircoglou, S. Bontemps, M. Mercy, N. Saffon, M. Takahashi, G. Bouhadir, L. Maron, D. Bourissou

 Angew. Chem. Int. Ed. 2007, 46, 8583-8586. Abstract



[4] P→B interaction within di- and tri-phosphineboranes

 S. Bontemps, G. Bouhadir, P. W. Dyer, K. Miqueu, D. Bourissou

 Inorg. Chem. 2007, 46, 5149-5149. Abstract



[3] Photoisomerizable Heterodienes derived from a Phosphine–Borane

 M. W. P. Bebbington, S. Bontemps, G. Bouhadir, D. Bourissou

 Angew. Chem. Int. Ed. 2007, 46, 3333-3336. Abstract



[2] On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR’2

 S. Bontemps, G. Bouhadir, K. Miqueu, D. Bourissou

 J. Am. Chem. Soc. 2006, 128, 12056-12057. Abstract



[1] Rhodium(I) Complexes of a PBP Ambiphilic Ligand : Evidence for a Metal→Borane Interaction

 S. Bontemps, H. Gornitzka, G. Bouhadir, K. Miqueu, D. Bourissou

 Angew. Chem. Int. Ed. 2006, 45, 1611-1614. Abstract