[47] Synthesis and coordination of a bisphosphine-[NHC-borane] compound: a ligand framework for bimetallic structure featuring a boron-bridging moiety
Aurèle Camy, Laure Vendier, Christian Bijani, Israel Fernández* and Sébastien Bontemps*
Inorg.
Chem., 2023, 62, 9035-9043, Abstract
[46] Alkaline Earth-Catalyzed CO2 Hydroboration into Acetal Derivatives Leading to C-S Bond Formation.
Wimonsiri Huadsai, Matthias Westerhausen,* Sébastien Bontemps*
Organometallics, 2023, 42, 2921-2926, Abstract
[45] CO2 Hydroboration: Impact of the Boryl Moieties on the Reactivity of Four Bis(boryl)acetal Compounds toward 2,6-Diisopropylaniline
Sarah Desmons, Yu Zhou, Dan Zhang, Carlos Jarava-Barrera, Anaïs Coffinet, Antoine Simonneau, Laure Vendier, Gen Luo,* Sébastien Bontemps*
Eur. J. Org. Chem., 2023, e202300525, Abstract
[44] Combined B-H and Si-H bond activations at ruthenium
Ramaraj Ayyappan, Koushik Saha, Urminder Kaur, Sourav Gayen, Laure Vendier, Sylviane Sabo-Etienne, Sundargopal Ghosh,* Sébastien Bontemps*
Organometallics, 2023, 42, 752-7561, Abstract
[43] Group IV Complexes with Sterically Congested N-Aryl-adamantylcarbamidate Ligands
Bahareh Rezaei Kheirkhah, Wimonsiri Huadsai, Phil Liebing, Sébastien Bontemps,* Matthias Westerhausen*
Organometallics, 2023, 42, 2304-2311, Abstract
[42] A masked form of an O-borylated Breslow intermediate for the diastereoselective FLP-type activation of aldehydes
Angelica Mejia Fajardo, Nicolas Queyriaux, Aurèle Camy, Laure Vendier, Mary Grellier, Iker del Rosal, Laurent Maron,* Sébastien Bontemps*
Chem. Eur.
J., 2022, e202104122, Abstract
[41] Synthesis and characterisation of a very low-coordinate diferrous [2Fe-2S](0) unit
Christian Schneider, Sophie Gross, Serhiy J. Demeshko, Sébastien Bontemps, Franc Meyer, C. Gunnar Werncke*
Chem. Commun., 2021, 57, 10751-10754, Abstract
[40] Enantioselective Reductive Oligomerization of Carbon Dioxide into L‑Erythrulose via a Chemoenzymatic Catalysis
Sarah Desmons,* Katie Grayson-Steel, Nelson Nuñez-Dallos, Laure Vendier, John Hurtado, Pere
Clapés,
Régis Fauré, Claire Dumon, and Sébastien Bontemps*
J. Am. Chem. Soc. 2021, 143, 39, 16274-16283, Abstract
[39] Selective Reductive Dimerization of CO2 into Glycolaldehyde
Dan Zhang, Carlos Jarava-Barrera, and Sébastien Bontemps*
ACS Catal. 2021, 11, 4568−4575, Abstract
[38] Impact of the Alkali Metal on the Structural and Dynamic Properties of the Anionic Pentahydride Ruthenium Complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na, K)
Ramaraj Ayyappan, Koushik Saha, Mary Grellier, Eric Clot, Laure Vendier, Sundargopal Ghosh, Sylviane Sabo-Etienne*, and Sébastien Bontemps*
Organometallics 2021, 40, 17, 3024–3032, Abstract
[37] Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition
Anaïs Coffinet, Dan Zhang, Laure Vendier, Sébastien Bontemps and Antoine Simonneau*
Dalton Trans. 2021, 50, 5582-5589, Abstract
[36] Synthesis and reactivity of phosphine borohydride compounds
R. Ayyappan, Y. Coppel, L. Vendier, S. Ghosh, S. Sabo-Etienne, S. Bontemps*
Chem. Comm. 2021, 57, 375 - 378, Abstract
[35] Quasilinear 3d-Metal(I) Complexes [KM(N(Dipp)SiR3)2] (M = Cr − Co) – Structural Diversity, Solution Behaviour and Reactivity
R. Weller, I. Müller, C. Duhayon, S. Sabo-Etienne, S. Bontemps, C. G. Werncke,*
Dalton Trans. 2021, 50, 4890-4903, Abstract
[34] Cooperative B–H and Si–H Bond Activations by κ2-N,S-Chelated Ruthenium Borate Complexes
M. Zafar, R. Ramalakshmi, A. Ahmad, P. K. S. *
Inorg. Chem. 2021, 60, 2, 1183–1194 Abstract
[33] NH3 formation from N2 and H2 mediated by molecular tri-iron complexes
M. Reiners, D. Baabe, K. Münster, M.-K. Zaretzke, M. Freytag, P. G. Jones, Y. Coppel, S. Bontemps, I. del Rosal, L. Maron, M. D. Walter*
Nat. Chem. 2020, 12, 740–746 Abstract
[32] Formaldehyde as a Promising C1 Source: the Instrumental Role of Biocatalysis for Stereocontrolled Reactions
S. Desmons, R. Fauré,* S. Bontemps*
ACS Catal. 2019, 9, 9575−9588, Abstract
[31] Versatile CO2 Transformations into Complex Products: a One-pot Two-step Strategy
S. Desmons, D. Zhang, A. Mejia Fajardo, S. Bontemps*
J. Vis. Exp. 2019 (153), e60348, Abstract
[30] Reductive CO2 homocoupling: synthesis of a borylated C3
carbohydrate
A. Bethegnies, Y. Escudié, N. Nunez-Dallos, L. Vendier, J. Hurtado, I. Del Rosal, L. Maron , S. Bontemps*
Chem. Cat. Chem. 2019, 11, 760-765, Abstract
[29] C-Halide bond cleavage by a two-coordinate iron(I) complex
C. G. Werncke,* J. Pfeiffer, I. Müller, L. Vendier, S. Sabo-Etienne, S. Bontemps
Dalton Trans., 2019, 48, 1757-1765, Abstract
[28] Ortho-Pheny dialkylphosphonium sulfonate compounds: two rotamers in equilibrium
E. Martin-Mothes, E. Puig, L. Vendier, C. Bijani, M. Grellier, S. Bontemps*
Dalton Trans. 2018, 47, 10139-10146, Abstract
[27] Crystal Structure and Magnetic Characterization of Three-Coordinate [M{N(SiMe3)2}2(PCyp3)] Complexes with M = MnII, FeII, and CoII (Cyp = Cyclopentyl)
C. G. Werncke, L. Vendier, S. Sabo-Etienne, J.-P. Sutter, C. Pichon,* S. Bontemps*
Eur. J. Inorg. Chem. 2017, 2017, 1041-1406, Abstract
[26] Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes
C. Gunnar Werncke, Mohammed-Amine Bouammali, Julie Baumard, Nicolas Suaud, Cyril Martins, Nathalie Guihéry,* Laure Vendier, Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel, Sylviane Sabo-Etienne, Jean-Pascal Sutter, Sébastien Bontemps* and Céline Pichon*
Inorg. Chem. 2016, 55, 21, 10968-10977, Abstract
[25] Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I)
C. Gunnar Werncke, Elizaveta Suturina, Philip C. Bunting, Laure Vendier, Jeffrey R. Long, Mihail Atanasov, Frank Neese,* Sylviane Sabo-Etienne and Sébastien Bontemps*
Chem., Eur. J. 2016, 22, 1668-1674. Abstract
[24] Boron-Mediated Activation of Carbon Dioxide
S. Bontemps*
Coord. Chem. Rev. 2016, 308, Part 2, 117-130. Abstract
[23] Iron-Catalyzed C–H Borylation of Arenes
T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps,* J.-B. Sortais,* S. Sabo-Etienne,* and C. Darcel*
J. Am. Chem. Soc. 2015, 137, 4062–4065
[22] Two-Coordinate Iron(I) Complex [Fe{N(SiMe3)2}2]−: Synthesis, Properties, and Redox Activity
C. G. Werncke, P. C. Bunting, C. Duhayon, J. R. Long, S. Bontemps,* S. Sabo-Etienne*
Angew. Chem. Int. Ed. 2015, 54, 245-248. Abstract
[21] Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C Bonds
G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne,* S. Bontemps*
J. Am. Chem. Soc. 2015, 137, 9563–9566. Abstract
[20] Three bonding modes of bis(2-picolyl)phenylphosphine at iron: isolation of a dinuclear iron complex featuring dearomatized pyridine moieties
G. Jin, L. Vendier, Y. Coppel, S Sabo-Etienne,* S. Bontemps*
Dalton Trans. 2015, 44, 7500-7505. Abstract
[19] Ruthenium-Catalyzed Reduction of Carbon Dioxide to Formaldehyde
S. Bontemps,* L. Vendier, S. Sabo-Etienne,*
J. Am. Chem. Soc. 2014, 136, 4419–4425. Abstract
[18] Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide
S. Bontemps,* S. Sabo-Etienne*
Angew. Chem. Int. Ed. 2013, 52, 10253-10255. Hot Paper. Abstract
[17] Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds
S. Bontemps, L. Vendier and S. Sabo-Etienne
Angew. Chem. Int. Ed. 2012, 51, 1671-1674.Abstract
[16] Comparative Reactivity of Zr– and Pd–Alkyl Complexes with Carbon Dioxide
K.-C. Lau, B. J. Petro, S. Bontemps, R. F. Jordan
Organometallics 2013, 32, 6895-6898. Abstract
[15] Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P→B Interactions
S. Bontemps, M. Devillard, S. Mallet-Ladeira, G. Bouhadir, K. Miqueu, D. Bourissou
Inorg. Chem. 2013, 52, 4714-4720. Abstract
[14] Palladium-Catalyzed Aryl Iodide Carbonylation as a Route to Imidazoline Synthesis: Design of a Five-Component Coupling Reaction
S. Bontemps, J. S. Quesnel, K. Worrall, B. A. Arndtsen
Angew. Chem. Int. Ed. 2011, 50, 8948-8951. Abstract
[13] A Palladium-Catalyzed Multicomponent Synthesis of Imidazolinium Salts and Imidazolines from Imines, Acid Chlorides and Carbon Monoxide
K.Worrall, B. Xu, S. Bontemps, B. A. Arndtsen
J. Org. Chem. 2011, 76, 170-180. Abstract
[12] A 1,1’-ferrocenyl phosphine-borane : synthesis, structure and evaluation in Rh-catalyzed hydroformylation
M. W. P. Bebbington, S. Bontemps, G. Bouhadir, M. J. Hanton, R. P. Tooze, H. van Rensburg, D. Bourissou
New J. Chem. 2010, 34, 1556-1559. Abstract
[11] Copper(I) Complexes derived from Mono- and Diphosphino-Boranes : Cu→B Interactions Supported by Arene Coordination
M. Sircoglou, S. Bontemps, M. Mercy, K. Miqueu, S. Ladeira, N. Saffon, L. Maron, G. Bouhadir, D. Bourissou
Inorg. Chem. 2009 ,49, 3983-3990. Abstract
[10] Bridging M-Cl Bonds with Ambiphilic Phosphine–Borane Ligands
S. Bontemps, G. Bouhadir, D. Apperley, P. W. Dyer, K. Miqueu, D. Bourissou
Chem. Asian J. 2009, 4, 428-435. Abstract
[9] Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane
M. Sircoglou, S. Bontemps, G. Bouhadir, N. Saffon, K. Miqueu, W. Gu, M. Mercy, C-H. Chen, B. Foxman, L. Maron, O. Ozerov, D. Bourissou
J. Am. Chem. Soc. 2008, 130, 16729-16738. Abstract
[8] Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes
X. Zhou, S. Bontemps, R. F. Jordan
Organometallics 2008, 27, 4821-4824. Abstract
[7] Metallaboratranes Derived from a Triphosphanyl-Borane : Intrinsic C3 Symmetry Supported by a Z-Type Ligand
S. Bontemps, G. Bouhadir, W. Gu, M. Mercy, C-H. Chen, B. M. Foxman, L. Maron, O. Ozerov, D. Bourissou
Angew. Chem. Int. Ed. 2008, 47, 1481-1484. Abstract
[6] Ambiphilic Diphosphine-Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium
S. Bontemps, M. Sircoglou, G. Bouhadir, H. Puschmann, J. A. K. Howard, P. Dyer, K. Miqueu, D. Bourissou
Chem. Eur. J. 2008, 14, 731-740. Abstract
[5] Transition-Metal Complexes Featuring Z-Type Ligands: Agreement or Discrepancy between Geometry and dn Configuration?
M. Sircoglou, S. Bontemps, M. Mercy, N. Saffon, M. Takahashi, G. Bouhadir, L. Maron, D. Bourissou
Angew. Chem. Int. Ed. 2007, 46, 8583-8586. Abstract
[4] P→B interaction within di- and tri-phosphineboranes
S. Bontemps, G. Bouhadir, P. W. Dyer, K. Miqueu, D. Bourissou
Inorg. Chem. 2007, 46, 5149-5149. Abstract
[3] Photoisomerizable Heterodienes derived from a Phosphine–Borane
M. W. P. Bebbington, S. Bontemps, G. Bouhadir, D. Bourissou
Angew. Chem. Int. Ed. 2007, 46, 3333-3336. Abstract
[2] On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR’2
S. Bontemps, G. Bouhadir, K. Miqueu, D. Bourissou
J. Am. Chem. Soc. 2006, 128, 12056-12057. Abstract
[1] Rhodium(I) Complexes of a PBP Ambiphilic Ligand : Evidence for a Metal→Borane Interaction
S. Bontemps, H. Gornitzka, G. Bouhadir, K. Miqueu, D. Bourissou
Angew. Chem. Int. Ed. 2006, 45, 1611-1614. Abstract